Use Master
GO
IF EXISTS (SELECT name FROM sys.databases WHERE name = N'UserImages')
DROP DATABASE UserImages
GO

USE master
GO

CREATE DATABASE [UserImages] ON PRIMARY 
( NAME = N'UserImages_Primary', FILENAME = N'D:\Program Files\Microsoft SQL Server\MSSQL10.MSSQLSERVER\MSSQL\DATA\UserImages.mdf', 
SIZE = 11520KB , MAXSIZE = UNLIMITED, FILEGROWTH = 1024KB )
LOG ON 
( NAME = N'UserImages_Log', FILENAME = N'E:\Program Files\Microsoft SQL Server\MSSQL10.MSSQLSERVER\MSSQL\Data\UserImages_1.ldf' , 
SIZE = 32448KB , MAXSIZE = 2048GB , FILEGROWTH = 10%)
GO

ALTER DATABASE [UserImages] 
ADD FILEGROUP [FileStreamGroup] CONTAINS FILESTREAM 
GO

ALTER DATABASE [UserImages] 
ADD FILE (NAME = N'UserImages_FileGroup', FILENAME = N'D:\Program Files\Microsoft SQL Server\MSSQL10.MSSQLSERVER\MSSQL\DATA\UserImages_2.UserImages')
TO FILEGROUP FileStreamGroup
GO